In a not quite wholly unrelated topic, I’ve just been reading about Ikaite and Glendonite. Ikaite is an extremely rare mineral which, uniquely, forms in very cold conditions in water. Minerals normally tend to form by either simple concentration-dependant precipitation from solutions percolating through rocks, or by differential cooling of extremely hot “solutions” of molten rock.
Ikaite is also unique in the fact that if you remove it from nearly-freezing water, it just melts away, leaving a sludge of commonplace calcium carbonate and some water. It’s not thermally unstable in the way water is, rather it’s an irreversible chemical reaction that happens to be temperature dependant.
It requires the mixing of two very specific kinds of mineral-laden water, and the mix needs to include nucleation preventers, such as phosphate ions, or again, you’ll just get CaCO3. When conditions are exactly right - and that pretty much means in one part of Ikka Fjord in Greenland - then you end-up with tall, thin natural columns or chimneys rising-up from the seafloor, as much 18m - until they reach about 2m below the surface - at which depth the winter ice pack extends downwards and knocks the tops off.
You get “fossilised” Ikaites in the form of Glendonites - these are simple calcite pseudomorphs, i.e. natural casts of long-vanished crystals of other materials, in this case Ikaite. Nearer to home, Jarrowite is a Glendonite which formed in the estuarine muds of the Tyne during the last Ice Age.
Much older ~55 million year old Glendonites in Denmark though have just been linked to volcanic activity (itself related to the Great Glen Fault - an abortive opening of the Atlantic along the line Loch Ness &seq), which though occurring during a period very warm climate, may have precipitated a series of previously undetected, localised, Early Eocene ice ages - geologically-brief episodes which were cold enough to have formed Ikaites.
…Aaaand all that’s got me thinking about some mysterious pipe-like structures in sandstones in Dorset, for which no remotely adequate explanation currently exists… The sedimentology and existing geochem is all wrong - but the structures, the age, and the underlying geological framework is highly compelling…